hi,
if,
tail -f /var/log/maillog file
SASL LOGIN authentication failed: UGFzc3dvcmQ6
fixed
nano /etc/dovecot/dovecot-mysql.conf
driver = mysql
connect = host=localhost dbname=postfix user=postfix password=xxxxxxxxxx
#default_pass_scheme = MD5-CRYPT
default_pass_scheme = PLAIN-MD5
remove md5-crypt
add plain-md5
thats it...